姓名：韩秋霞
职称：教授
导师情况：硕士/博士生导师
研究方向：多酸基功能配合物；多酸催化
办公室：304am永利集团118室
E-Mail：hdhqx@henu.edu.cn
课题组网站：https://www.x-mol.com/groups/han_qx118
韩秋霞，教授、博士生导师。大连理工大学博士（2015），河南大学博士后（2019）。2020年获河南省优青，2020年开封市科技创人才，2021年获河南省教育厅学术带头人，2022年获开封市科技创团队带头人。
长期从事无机化学、多酸化学和催化化学的交叉性研究工作，特别是以多酸基金属有机框架（POMOFs）晶态多孔功能材料为研究平台，围绕催化中心微环境的化学调控方面开展了较为系统的研究工作，部分研究成果获2020年度河南省自然科学三等奖（第一完成人）。研究结果已在国际重要SCI期刊上发表论文50余篇，部分发表在J. Am. Chem. Soc.、Nat. Commun.、J. Catal.、Chem. Commun.、Inorg. Chem.、ACS Appl. Mater. Interfaces等国际知名期刊上；获授权发明专利8项。
承担的主要项目:
1. 国家自然科学基金青年项目，21601048，多酸基手性功能材料的制备及不对称串联催化烯烃制备环状碳酸酯的研究，2017.01-2019.12，25万元，完成
2. 国家自然科学基金-河南人才培养联合基金，U1304201，基于多金属氧酸盐的手性金属有机框架在不对称催化缺电子烯烃环氧化中的应用，2014.01-2016.12，30万元，结项
3. 河南省优秀青年科学基金，手性光催化剂的合成及光氧化还原催化醛酮的不对称α-烷基化研究，2020.10-2023.09，202300410043，25万，在研
4. 河南省高等学校重点科研项目，20zx006，新型多功能手性催化剂的合成及在不对称光催化高效合成重要化学品中的应用，30万，2020.01-2021.12，在研
5. 中国博士后科学基金第 58 批面上一等资助，2015M580626，多酸MOF材料的设计及不对称串联催化制备环氧酮的研究，2015.12-2017.12，8万元，结项
6. 河南省自然科学基金面上项目，162300410012，多酸基手性功能材料的制备及不对称串联催化烯烃制备环状碳酸酯的研究，2017.01-2018.12，10万元，结项
7. 河南省科技发展计划项目，162102210171，多酸基手性多孔材料不对称催化烯烃环氧化研究，2016.01-2017.12，结项
8. 河南大学一流学科培育项目，2019YLZDJL10，多酸功能材料的定向制备及催化性能研究，2020.01-2021.09，20万元，在研
9. 河南大学优青培育项目，yqpy20140011，基于多金属氧酸盐的手性金属有机框架在不对称催化缺电子烯烃环氧化中的应用，2014.04-2019.04，25万元，结项
代表性成果
代表性论文（按时间倒序）：
2020年-至今
1. Jiachen Jiao, Ting Zhang, Jiangbo Xu, Kaixin Guo, Jie Li and Qiuxia Han,* Hydroxyl Radical-dominated Selective Oxidation of Ethylbenzene over a Photoactive Polyoxometalate-based Metal-organic Framework, Chem. Commun., 2023, https://doi.org/10. 1039/d2cc06403k
2. Chen Si, Xueling Liu, Ting Zhang, Jiangbo Xu, Jie Li, Jiya Fu,* Qiuxia Han,* Constructing a Photocatalyst for Selective Oxidation of Benzyl Alcohol to Benzaldehyde by Photo-Fenton-like Catalysis, Inorg.Chem., 2023, accepted.
3. Xiaomei Yan, Jiangbo Xu, Ting Zhang, Chen Si, Jiachen Jiao, Jie Li, Qiuxia Han,*Designing polyoxometalate-based metal-organic framework for oxidation of styrene and cycloaddition of CO2 with epoxides, Chinese Chem. Lett., 2023 https://doi.org/10.1016/j.cclet.2022.107851
4. Ting Zhang, Chen Si, Kaixin Guo, Xueling Liu, Qingchao Liu, Jiya Fu,* and Qiuxia Han,* Constructing a Redox-Active Cu(I)-Pyridyltriazine Framework for Catalytic Photoreduction of Nitrobenzenes and Carboxylic Cyclization of Alkynol with CO2, Inorg. Chem., 2022, 61, 20657−20665. https://doi.org/10.1021/acs.inorgchem.2c03627
5. Jiachen Jiao, Hui Sun, Chen Si, Jiangbo Xu, Ting Zhang, Qiuxia Han,* Photocatalytic Multielectron Reduction of Nitroarenes to Anilines by Utilizing Electron-storable Polyoxometalate-based Metal-organic Framework, ACS Appl. Mater. Interfaces, 2022, 14, 16386−16393. https://pubs.acs.org/doi/10.1021/acsami.1c24911.
6. Chen Si, Fan Liu, Xiaomei Yan, Jiangbo Xu, Guiqin Niu, Qiuxia Han,* Designing Polyoxometalate-incorporated Metal-organic Frame-work for Reduction of Nitroarenes to Anilines by Sequential Proton-Coupled Electron Transfers, Inorg. Chem., 2022, 61, 5335−5342. https://doi.org/10.1021/acs.inorgchem.2c00106
7. Jiachen Jiao, Xiaomei Yan, Songzhu Xing, Ting Zhang, and Qiuxia Han,* Design of a Polyoxometalate-Based Metal−Organic Framework for Photocatalytic C(sp3 )−H Oxidation of Toluene, Inorg. Chem., 2022, 61, 2421−2427. https://pubs.acs.org/10.1021/acs.inorgchem.1c03150
8. Xiaomei Yan, Zhuolin Shi, Jiachen Jiao, Chen Si, Qiuxia Han*, An Isopolymolybdate-Incorporated Metal−Organic Framework with Sulfite Oxidase-Mimicking Activity for Photocatalytic Oxidation of Sulfides Utilizing In Situ-Generated Singlet Oxygen, Inorg. Chem., 2021, 60, 16810−16816. https://doi.org/10.1021/acs.inorgchem.1c02701
9. Chen Si, Pengtao Ma,* Qiuxia Han,* Jiachen Jiao, Wei Du, Jingpin Wu, Mingxue Li, and Jingyang Niu*. A Polyoxometalate-based Inorganic Porous Material with both Proton and Electron Conductivity by Light Actuation: Photocatalysis for Baeyer−Villiger Oxidation and Cr(VI) Reduction. Inorg. Chem., 2021, 60, 682−691. https://dx.doi.org/10.1021/acs.inorgchem.0c02658
10. Jie Li, Jiachen Jiao, Jiangnan Chang, Mingxue Li,* and Qiuxia Han,* Visible-Light-Driven C−N Bond Formation by a Hexanickel Cluster Substituted Polyoxometalate-Based Photocatalyst, Inorg. Chem., 2021, 60, 10022-10029. https://doi.org/10.1021/acs.inorgchem.1c01311
11. Jiachen He, Jie Li, Qiuxia Han,* Chen Si, Guiqin Niu, Mingxue Li, Jingping Wang, Jingyang Niu, Photoactive Metal-Organic Framework for the Reduction of Aryl Halides by the Synergistic Effect of Consecutive Photo-Induced Electron-Transfer and Hydrogen-Atom Transfer Processes, ACS Appl. Mater. Interfaces, 2020, 12, 2199−2206. https://doi.org/10.1021/acsami.9b13538
12. Jie Li, Jiachen He, Chen Si, Mingxue Li,* Qiuxia Han,* Ziliang Wang, Junwei Zhao，Special-Selective C–H Oxidation of Toluene To Benzaldehyde by a Hybrid Polyoxometalate Photocatalyst Including a Rare [P6W48Fe6O180]30– Anion, J Catal., 2020, 392, 244–253. https://doi.org/10.1016/j.jcat.2020.10.013
13. Guiqin Niu, Chen Si, Jiachen Jiao, Qiuxia Han,* Mengfei Guo , Mingxue Li,* An Electron-Rich Metal-Organic Framework for Highly Efficient Photocatalytic Reduction of Cr(VI), J. Alloy. Compd., 2020, 830, 154696. https://doi.org/10.1016/j.jallcom.2020.154696
14. Zhuolin Shi, Jiachen Jiao, Qiuxia Han,* Yang Xiao, Laikuan Huang, Mingxue Li. Synthesis Cu(I)–CN-based MOF with in-situ generated cyanogroup by cleavage of acetonitrile: Highly efficient for catalytic cyclization of propargylic alcohols with CO2. Mol. Catal., 2020, 496, 111190. https://doi.org/10.1016/j.mcat.2020.111190
2020年以前
15. Jiachen He,† Qiuxia Han,*,† Jie Li, Zhuolin Shi, Xiaoyun Shi, Jingyang Niu,* Ternary Supramolecular System for Photocatalytic Oxidation with Air by Consecutive Photo-induced Electron Transfer Processes, J. Catal., 2019, 376, 161–167. https://doi.org/10.1016/j.jcat.2019.06.040
16. Zhuolin Shi, Jie Li, Qiuxia Han,* Xiaoyun Shi, Chen Si, Guiqin Niu, Pengtao Ma, and Mingxue Li, Polyoxometalate-Supported Aminocatalyst for the Photocatalytic Direct Synthesis of Imines from Alkenes and Amines, Inorg. Chem., 2019, 58, 12529−12533. https://doi.org/10.1021/acs.inorgchem.9b02056
17. Jiachen He, Jie Li, Wei Du, Qiuxia Han,* Ziliang Wang and Mingxue Li*, A Mesoporous Metal- Organic Framework: Potential Advances in Selective Dye Adsorption, J. Alloy. Compd., 2018, 750, 360−367. https://doi.org/10.1016/j.jallcom.2018.03.393
18. Songzhu Xing, Jie Li, Guiqin Niu, Qiuxia Han,* Jingjing Zhang, Hongling Liu*, Chiral and Amine Groups Functionalized Polyoxometalate-based Metal-organic Frameworks for Synergic Catalysis in Aldol and Knoevenagel Condensations, Mol. Catal., 2018, 458, 83–88. https://doi.org/10.1016/j.mcat.2018.08.011
19. Zhuolin Shi, Guiqin Niu, Qiuxia Han,* Xiaoyun Shi, Mingxue Li,* A Molybdate-incorporated Cooperative Catalyst: High Efficiency in the Assisted Tandem Catalytic Synthesis of Cyclic Carbonates from CO2 and Olefins, Mol. Catal., 2018, 10, 10–18. https://doi.org/10.1016/j.mcat.2018.10.003
20. Songzhu Xing,† Qiuxia Han,*,† Zhuolin Shi, Shugai Wang, PeiPei Yang, Qiang Wu and Mingxue Li,* A Hydrophilic Inorganic Framework Based on Sandwich Polyoxometalate: Unusual Chemoselectivity for Aldehydes/Ketones with in situ generated hydroxylamine, Dalton T., 2017, 46, 11537–11541. https://pubs.rsc.org/en/content/articlelanding/2017/dt/c7dt02411h
21. Qiuxia Han,*,† Wenwen Li,† Shugai Wang, Jiachen He, Mingxue Li*, Asymmetric Cascade Catalysis with Chiral Polyoxometalate-based Frameworks: Sequential Direct Aldol and Epoxidation Reactions, ChemCatChem, 2017, 9, 1801–1807. https://doi.org/10.1002/cctc.201700160
22. Qiuxia Han, Bo Qi, Weimin Ren, Cheng He, Jingyang Niu, Chunying Duan.* Polyoxometalate-Based Homochiral Metal-Organic Frameworks for Tandem Asymmetric Transformation of Cyclic Carbonates from Olefins. Nat. Commun., 2015, 6, 10007. https://www.nature.com/articles/ncomms10007
23. Qiuxia Han,* Xueping Sun, Jie Li, Pengtao Ma, Jingyang Niu.* Novel Isopolyoxotungstate [H2W11O38]8− Based Metal Organic Framework: as Lewis Acid Catalyst for Cyanosilylation of Aromatic Aldehydes. Inorg. Chem., 2014, 53, 6107−6112. https://pubs.acs.org/doi/10.1021/ic5004879
24. Qiuxia Han,* Xueping Sun, Jie Li, Pengtao Ma, Jingyang Niu.* Beat over the Old Ground with New Strategy: Engineering As···As Interaction in Arsenite-based Dawson Cluster β‑[W18O54(AsO3)2]6−. Inorg. Chem., 2014, 53, 2006−2011. https://pubs.acs.org/doi/10.1021/ic402179u
25. Qiuxia Han, Cheng He, Min Zhao, Bo Qi, Jingyang Niu, Chunying Duan.* Engineering Chiral Polyoxometalate Hybrid Metal−organic Frameworks for Asymmetric Dihydroxylation of Olefins. J. Am. Chem. Soc., 2013, 135, 10186−10189. https://pubs.acs.org/doi/10.1021/ja401758c
26. Qiuxia Han,* Lejie Zhang, Cheng He, Jiangyang Niu, Chunying Duan.* Metal-Organic Frameworks with Phosphotungstate Incorporated for Hydrolytic Cleavage of a DNA-Model Phosphodiester. Inorg. Chem., 2012, 51, 5118−5127. https://pubs.acs.org/doi/full/10.1021/ic202685e
27. Qiuxia Han, Pengtao Ma, Junwei Zhao, Ziliang Wang, Wenhua Yang, Penghu Guo, Jingping Wang*, and Jingyang Niu*, Three Novel Inorganic−Organic Hybrid Arsenomolybdate Architectures Constructed from Monocapped Trivacant [AsIIIAsVMo9O34]6− Fragments with [Cu(L)2]2+ Linkers: From Dimer to Two-Dimensional Framework, Cryst. Growth Des., 2011, 11, 2, 436–444. https://pubs.acs.org/doi/10.1021/cg101125m
发明专利（第一发明人）：
1. 韩秋霞;韦爱芬;宫德龙;焦嘉晨;司晨,一类缺位型多酸基金属有机框架分子材料及其在光催化选择性还原硝基苯的应用, 中国，发明专利，专利号：ZL 202210009328.4, 授权日期：2023.2.12。
2. 韩秋霞，马鹏涛，李杰，何佳宸，司晨，一种手性多酸基金属有机框架材料及其制备方法和应用, 中国，发明专利，专利号：ZL 2019 1 0209209.1, 授权日期：2021.10.12。
3. 韩秋霞，陈淑敏，马鹏涛，牛桂琴，司晨，一类富电子体系的金属有机框架分子材料及其在光催化还原重金属离子中的应用，中国，发明专利，专利号：ZL 2019 1 1324193.5，授权日期：2021.06.29。
4. 韩秋霞，李明雪，李杰，史卓林，司晨，基于Zn取代Keggin型杂多钨酸盐的有机-无机复合物、合成方法及应用，中国，发明专利，专利号：ZL 2019 1 0496900.2，授权日期：2021.04.23。
5. 韩秋霞，李明雪，李杰，邢松珠，王书改，一种亲水性无机多孔材料、制备方法及其在选择性催化醛或酮与羟胺反应方面的应用，中国，发明专利，专利号：ZL 2017 1 0352407.4，授权日期：2019.07.05。
获奖情况：
1. 河南省自然科学奖三等奖，多酸基金属-有机框架的定向制备和限域空间内的协同催化, 证书号：2020-Z-022-R01/03，2020，第一完成人
